Volume 95,   №7

KINETIC LAWS GOVERNING THERMAL DECOMPOSITION OF PERCHLORATE NICKEL ORGANOMETALLIC COMPLEXES UNDER CHANGES OF THE LIGAND NATURE



As a result of the interaction of nickel perchlorate with ethylenediamine, imidazole, and semicarbazide, complex compounds Ni(En)3(ClO4)2, Ni(Im)6(ClO4)2, and Ni(SC)3(ClO4)2 have been obtained, the structure and composition of which were confi rmed by elemental analysis and by the method of the infrared spectroscopy of frustrated total internal refl ection. The kinetics of the thermal decomposition of synthesized compounds in an inert medium was studied within the framework of the traditional method of thermal analysis in a helium atmosphere at a rate of the heating of samples of 5o C/min and under conditions of their high-speed heating (>100o C/min) with simultaneous determination of the composition of gaseous products of thermal decomposition of the material.
 
 
Author:  A. G. Shmakov, A. A. Paletskii, O. V. Komova, S. A. Mukha, K. A. Dmitruk, O. V. Netskina
Keywords:  organometallic complexes, ethylenediamine, imidazole, semicarbazide, perchlorate nickel, thermal decomposition kinetics
Page:  1732

Link
A. G. Shmakov, A. A. Paletskii, O. V. Komova, S. A. Mukha, K. A. Dmitruk, O. V. Netskina.  KINETIC LAWS GOVERNING THERMAL DECOMPOSITION OF PERCHLORATE NICKEL ORGANOMETALLIC COMPLEXES UNDER CHANGES OF THE LIGAND NATURE //Journal of engineering physics and thermophysics. . Volume 95, №7. P. 1732.


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