INFLUENCE OF BINARY ADDITIVES OF COMPATIBILIZERS ON THE MICRO- AND MACRORHEOLOGICAL PROPERTIES OF MELTS OF POLYPROPYLENE-COPOLYAMIDE MIXTURES
V. G. Rezanova and M. V. Tsebrenko UDC 546.64:532.135 We have investigated the influence of binary additives of compatibilizers copolymer of ethylene with vinyl acetate/siloxane liquid on the rheological properties of melts and the processes of structure formation in polypropylene-copolyamide mixtures. It has been shown that there exists an optimal ratio of compatibilizers at which the maximum influence of additives on the process of specific fiber formation shows up. The mechanism of their action is connected with an increase in the length of the interphase layer, a decrease in the surface tension, and an increase in the lifetime of the liquid jet. The use of compatibilizers influences the viscosity of melts only slightly, and the capability of four-component compositions to be processed markedly increases. Kiev National University of Technologies and Design, 2 Nemirovich-Danchenko Str., Kiev, 01011, Ukraine; email: vlasenko@ekma.Kiev.ua. Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 81, No. 4, pp. 737-743, July-August, 2008. Original article submitted March 12, 2007.